The loveably nerdish David Mitchell guest-hosts the satirical current affairs quiz, and is joined by artist Grayson Perry and comedian Ed 'The Teeth' Byrne who accompany team captains Ian Hislop and Paul Merton. Jonathan Ross's show can be seen at 11.10pm (damn you, Friday Show *shakes fist*), and he continues the new season of music and chat with a line-up comprising rock 'n' roll comic Tim Minchin; one of the biggest rappers on the planet, 50 Cent; Gavin and Stacey star Joanna Page; the inimitable Boy George in his first interview since his release from prison; and there's music from Jamie Cullum