Valencia v Chelsea (Kick-off 7.45pm). Here is this evening's Group E encounter at the Mestalla, where the Blues are looking to continue their winning start to their Champions League campaign. Second-half goals by David Luiz and Juan Mata earned Chelsea a 2-0 home win against Bayer Leverkusen in their opening fixture, while the Spaniards failed to break down Genk on their travels and had to settle for a goalless draw. With commentary by Stephen Alkin and Trevor Steven. Plus, highlights of Arsenal v Olympiakos at the Emirates Stadium. There's UEFA Champions League: Extra Time on ITV1 from 10.35pm.