Of all the bands that you'd picture doing a James Bond theme, Radiohead might be the most unlikely.
The British band don't really scream Tom Ford suits, explosions and shagging Bond girls, but maybe that would've been part of the allure. Ultimately Sam Smith performed the hit single, 'Writing's On the Wall' but Radiohead were apparently asked first by producers saying simply "it didn't work out."
They have since released the song, also called 'Spectre,' so fans can have a butchers for themselves.